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Title: | 3-(2-BENZOTHIAZOLYLAZO)THENOYLTRIFLUORO ACETONE AND ITS Cu(II), Co(II), Ni(II) AND Zn(II) COMPLEXES |
Authors: | Muhammed Basheer Ummathur ParakkulangaraThrithodi Malini Damodaran Kamalakshy Babu Krishnannair Krishnankutty |
Keywords: | Benzothiazolylazo Derivative, Thenoyltrifluoroacetone, Azo-enol Form, Metal Complexes, Spectral Studies. |
Issue Date: | Sep-2021 |
Publisher: | Rasayan Journal of Chemistry |
Abstract: | The coupling of diazotized 2-aminobenzothiazole with thenoyltrifluoroacetone resulted in the formation of a tridentate ligand (HL). Azo-enol tautomeric form of the compound with intramolecular hydrogen bond is confirmed by spectral and analytical data. Formation of its [CoL2], [NiL2], [CuL(OAc)] and [ZnL2] complexes with monobasic tridentate coordination is also proposed based on analytical and spectral data. Magnetic studies revealed that Cu(II), Ni(II) and Co(II) complexes are paramagnetic while the Zn(II) chelate is diamagnetic. |
URI: | http://dspace.unitywomenscollege.ac.in/xmlui/handle/123456789/1883 |
ISSN: | 0974-1496 |
Appears in Collections: | Journal Articles |
Files in This Item:
File | Description | Size | Format | |
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Prof. Dr. Basheer Ummathur.pdf | 900.8 kB | Adobe PDF | View/Open |
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